Diethylamine → 2-[3-[(tert-Butyldiphenylsilyl)oxy]propynyl)-7,8,9,10-tetrahydrophenanthridine

HRID 170576Notes

Reaction equation

HRID 170576 reaction equation
[C:23]([CH3:24])([CH3:25])([CH3:26])[Si:27]([O:28][CH2:29][C:30]#[CH:31])([c:32]1[cH:33][cH:34][cH:35][cH:36][cH:37]1)[c:38]1[cH:39][cH:40][cH:41][cH:42][cH:43]1.[CH2:44]([NH:45][CH2:46][CH3:47])[CH3:48].[CH3:49][CH2:50][O:51][C:52](=[O:53])[CH3:54].[Cu:55][I:56].[F:1][C:2]([F:3])([F:4])[S:5]([O:6][c:7]1[cH:8][c:9]2[c:10]3[c:15]([cH:16][n:17][c:18]2[cH:19][cH:20]1)[CH2:14][CH2:13][CH2:12][CH2:11]3)(=[O:21])=[O:22]>>[c:7]1([C:31]#[C:30][CH2:29][O:28][Si:27]([C:23]([CH3:24])([CH3:25])[CH3:26])([c:32]2[cH:33][cH:34][cH:35][cH:36][cH:37]2)[c:38]2[cH:39][cH:40][cH:41][cH:42][cH:43]2)[cH:8][c:9]2[c:10]3[c:15]([cH:16][n:17][c:18]2[cH:19][cH:20]1)[CH2:14][CH2:13][CH2:12][CH2:11]3

Participants

6

Reactant 5

HCID 8021DiethylamineHCID 8857Ethyl AcetateHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 610226Silane, (1,1-dimethylethyl)diphenyl(2-propynyloxy)-HCID 156780692-[(Trifluoromethanesulfonyl)oxy]-7,8,9,10-tetrahydrophenanthridine

Product 1

HCID 156780702-[3-[(tert-Butyldiphenylsilyl)oxy]propynyl)-7,8,9,10-tetrahydrophenanthridine

Sources & evidence

ORD record
ord-57262472448347de821befb20990fb71
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (9/10)

Reaction notes

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