Tris(hydroxymethyl)aminomethane → HCID 131718742, compound

HRID 1708234Notes

Reaction equation

HRID 1708234 reaction equation
[CH3:1][C:2]([C:4]([O:6][CH2:7][CH2:8][N:9]([CH3:11])[CH3:10])=[O:5])=[CH2:3].[CH2:12]([OH:19])[C:13]([NH2:18])([CH2:16][OH:17])[CH2:14][OH:15]>CCOC(C)=O>[CH3:3][C:2]([C:4]([O:6][CH2:7][CH2:8][N:9]([CH3:11])[CH3:10])=[O:5])=[CH2:1].[CH2:12]([OH:19])[C:13]([NH2:18])([CH2:16][OH:17])[CH2:14][OH:15]

Participants

4

Reactant 2

HCID 6503Tris(hydroxymethyl)aminomethaneHCID 17869(Dimethylamino)ethyl methacrylate

Product 1

HCID 131718742HCID 131718742, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

Into a 946 ml clear bottle were charged VDM (20 parts), DMAEMA (75 parts), Tris (5 parts), XDC (4.0 parts) and 100 parts of EtOAc. The solution was purged for 10 minutes, the bottle was sealed, placed on a roller mill, and irradiated with a bank of six GE 15 watt cylindrical black light lamps. The mixture became progressively more viscous. After 24 hours of irradiation the bottle was removed. Quantitative conversion was achieved as shown by a percent solids analysis.

Workup

  1. customThe solution was purged for 10 minutes
  2. customthe bottle was sealed
  3. customirradiated with a bank of six GE 15 watt cylindrical black light lamps
  4. customAfter 24 hours of irradiation the bottle
  5. customwas removed

Sources & evidence

ORD record
ord-99330b8492ff4008a2c5386787511733
Source dataset
uspto-grants-1994_10
Patent number
US05356947

Reaction notes

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