1-Dodecanethiol → 2,4-bis[N,N-bis(2,2,6,6-tetramethyl-4-piperidyl)amino]-6-[n-dodecylthio]-1,3,5-triazine

HRID 1709354Notes

Reaction equation

HRID 1709354 reaction equation
[CH2:1]([SH:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Na].[CH3:15][C:16]1([CH3:63])[CH2:21][CH:20]([N:22]([C:33]2[N:38]=[C:37]([N:39]([CH:50]3[CH2:55][C:54]([CH3:57])([CH3:56])[NH:53][C:52]([CH3:59])([CH3:58])[CH2:51]3)[CH:40]3[CH2:45][C:44]([CH3:47])([CH3:46])[NH:43][C:42]([CH3:49])([CH3:48])[CH2:41]3)[N:36]=[C:35](Cl)[N:34]=2)[CH:23]2[CH2:28][C:27]([CH3:30])([CH3:29])[NH:26][C:25]([CH3:32])([CH3:31])[CH2:24]2)[CH2:19][C:18]([CH3:62])([CH3:61])[NH:17]1>C1(C)C(C)=CC=CC=1>[CH3:58][C:52]1([CH3:59])[CH2:51][CH:50]([N:39]([C:37]2[N:38]=[C:33]([N:22]([CH:23]3[CH2:28][C:27]([CH3:30])([CH3:29])[NH:26][C:25]([CH3:32])([CH3:31])[CH2:24]3)[CH:20]3[CH2:21][C:16]([CH3:15])([CH3:63])[NH:17][C:18]([CH3:62])([CH3:61])[CH2:19]3)[N:34]=[C:35]([S:13][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[N:36]=2)[CH:40]2[CH2:41][C:42]([CH3:48])([CH3:49])[NH:43][C:44]([CH3:46])([CH3:47])[CH2:45]2)[CH2:55][C:54]([CH3:57])([CH3:56])[NH:53]1

Participants

5

Reactant 3

HCID 81951-DodecanethiolHCID 5360545SodiumHCID 198957912,4-bis[N,N-bis(2,2,6,6-tetramethyl-4-piperidyl)amino]-6-chloro-1,3,5-triazine

Product 1

HCID 230376902,4-bis[N,N-bis(2,2,6,6-tetramethyl-4-piperidyl)amino]-6-[n-dodecylthio]-1,3,5-triazine

Reagents, catalysts & solvents 1

HCID 7237O-XyleneSolvent

Procedure

Following the procedure described in Example 11 and using 20.3 g (0.11 mol) of 1-dodecanthiol, 2.53 g (0.11 mol) of sodium and 70.25 g (0.1 mol) of 2,4-bis[N,N-bis(2,2,6,6-tetramethyl-4-piperidyl)amino]-6-chloro-1,3,5-triazine in 250 ml of xylene, the product of melting point 168°-170° C. is obtained.

Workup

  1. customthe product of melting point 168°-170° C. is obtained

Sources & evidence

ORD record
ord-2c2a5c927988420faa86137216922350
Source dataset
uspto-grants-1990_08
Patent number
US04948889

Reaction notes

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