HRID1709354

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID8195

1-Dodecanethiol

C12H26S

HCID5360545

Sodium

结构：CC1(C)CC(N(c2nc(Cl)nc(N(C3CC(C)(C)NC(C)(C)C3)C3CC(C)(C)NC(C)(C)C3)n2)C2CC(C)(C)NC(C)(C)C2)CC(C)(C)N1

HCID19895791

未命名化合物

PRODUCTS

生成物

结构：CCCCCCCCCCCCSc1nc(N(C2CC(C)(C)NC(C)(C)C2)C2CC(C)(C)NC(C)(C)C2)nc(N(C2CC(C)(C)NC(C)(C)C2)C2CC(C)(C)NC(C)(C)C2)n1

HCID23037690

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID7237

o-Xylene

C8H10

PROCEDURE

实验过程

Following the procedure described in Example 11 and using 20.3 g (0.11 mol) of 1-dodecanthiol, 2.53 g (0.11 mol) of sodium and 70.25 g (0.1 mol) of 2,4-bis[N,N-bis(2,2,6,6-tetramethyl-4-piperidyl)amino]-6-chloro-1,3,5-triazine in 250 ml of xylene, the product of melting point 168°-170° C. is obtained.

WORKUP

后处理

customthe product of melting point 168°-170° C. is obtained

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-2c2a5c927988420faa86137216922350
来源数据集: uspto-grants-1990_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04948889
来源说明: uspto-grants-1990_08

反应 SMILES

[CH2:1]([SH:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[Na].[CH3:15][C:16]1([CH3:63])[CH2:21][CH:20]([N:22]([C:33]2[N:38]=[C:37]([N:39]([CH:50]3[CH2:55][C:54]([CH3:57])([CH3:56])[NH:53][C:52]([CH3:59])([CH3:58])[CH2:51]3)[CH:40]3[CH2:45][C:44]([CH3:47])([CH3:46])[NH:43][C:42]([CH3:49])([CH3:48])[CH2:41]3)[N:36]=[C:35](Cl)[N:34]=2)[CH:23]2[CH2:28][C:27]([CH3:30])([CH3:29])[NH:26][C:25]([CH3:32])([CH3:31])[CH2:24]2)[CH2:19][C:18]([CH3:62])([CH3:61])[NH:17]1>C1(C)C(C)=CC=CC=1>[CH3:58][C:52]1([CH3:59])[CH2:51][CH:50]([N:39]([C:37]2[N:38]=[C:33]([N:22]([CH:23]3[CH2:28][C:27]([CH3:30])([CH3:29])[NH:26][C:25]([CH3:32])([CH3:31])[CH2:24]3)[CH:20]3[CH2:21][C:16]([CH3:15])([CH3:63])[NH:17][C:18]([CH3:62])([CH3:61])[CH2:19]3)[N:34]=[C:35]([S:13][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[N:36]=2)[CH:40]2[CH2:41][C:42]([CH3:48])([CH3:49])[NH:43][C:44]([CH3:46])([CH3:47])[CH2:45]2)[CH2:55][C:54]([CH3:57])([CH3:56])[NH:53]1