Ethyl Acetate → (E)-Hexadec-2-enal

HRID 1710173Notes

Reaction equation

HRID 1710173 reaction equation
CO[C:3]1[CH:4]=[CH:5][C:6]([CH:9]=[O:10])=[CH:7][CH:8]=1.C(O[CH2:15][CH3:16])(=O)C>>[CH:9](=[O:10])/[CH:6]=[CH:5]/[CH2:4][CH2:3][CH2:8][CH2:7][CH2:5][CH2:4][CH2:3][CH2:8][CH2:7][CH2:6][CH2:9][CH2:15][CH3:16]

Participants

3

Reactant 2

HCID 8857Ethyl AcetateHCID 312444-Methoxybenzaldehyde

Product 1

HCID 5280541(E)-Hexadec-2-enal

Procedure

RF =0.5, petroleum ether (boiling point 35°-80° C./ethyl acetate 9:1; UV: blue coloration with anisaldehyde reagent (0.5 ml anisaldehyde, 50 ml glacial acetic acid, 1 ml H2SO4); boiling point (10-3Torr): 115° C.

Workup

  1. custom115° C.

Sources & evidence

ORD record
ord-bec026266b6a4d05b3127586b960bf38
Source dataset
uspto-grants-1990_08
Patent number
US04952683

Reaction notes

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