Methyl Methacrylate → HCID 87918426, compound

HRID 1713953Notes

Reaction equation

HRID 1713953 reaction equation
[C:1]([O:6][CH3:7])(=[O:5])[C:2]([CH3:4])=[CH2:3].[CH3:8][CH:9]([NH:11][C:12]([CH:14]=[CH2:15])=[O:13])[CH3:10].N(C(C)(CC)C#N)=NC(C)(CC)C#N>C(OCC)(=O)C>[CH3:8][CH:9]([NH:11][C:12]([CH:14]=[CH2:15])=[O:13])[CH3:10].[C:1]([O:6][CH3:7])(=[O:5])[C:2]([CH3:4])=[CH2:3]

Participants

5

Reactant 3

HCID 6658Methyl MethacrylateHCID 16637N-IsopropylacrylamideHCID 930792,2'-Azobis(2-methylbutyronitrile)

Product 1

HCID 87918426HCID 87918426, compound

Reagents, catalysts & solvents 1

HCID 8857Ethyl AcetateSolvent

Procedure

A 25 ml reaction vessel was charged with 36 g ethyl acetate, 2.15 g (0.005 mol) TRIS, 1.58 g (0.016 mol) methyl methacrylate, 0.32 g (0.003 mol) NIPAM, and 0.078 g. 2,2′-azobis(2-methylbutanenitrile). After nitrogen flushing for 3 minutes, the vessel was closed and placed in an oil bath. The polymerization was run for 18 hours at 61-65° C. The polymer was precipitated into water and dried at room temperature (20° C.). The polymer was soluble in HMDS.

Workup

  1. customA 25 ml reaction vessel
  2. customthe vessel was closed
  3. customplaced in an oil bath
  4. waitThe polymerization was run for 18 hours at 61-65° C
  5. customThe polymer was precipitated into water
  6. customdried at room temperature (20° C.)

Sources & evidence

ORD record
ord-32a5ac8480fb4e17b3628cd69d808790
Source dataset
uspto-grants-2010_09
Patent number
US07795326B2

Reaction notes

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