1,1-Dimethylhydrazine → HCID 73794499, compound

HRID 1729606Notes

Reaction equation

HRID 1729606 reaction equation
[CH3:1][C:2]1[C:7]([CH3:8])=[CH:6][CH:5]=[CH:4][C:3]=1[N+:9]([O-:11])=O.CC1C(C)=CC=CC=1NO.[CH3:22][N:23]([NH2:25])[CH3:24]>>[CH3:22][N:23]([CH3:24])[N:25]=[N+:9]([O-:11])[C:3]1[CH:4]=[CH:5][CH:6]=[C:7]([CH3:8])[C:2]=1[CH3:1]

Participants

4

Reactant 3

HCID 59761,1-DimethylhydrazineHCID 67391,2-Dimethyl-3-nitrobenzeneHCID 145678Hydroxylamine, N-(2,3-xylyl)-

Product 1

HCID 73794499HCID 73794499, compound

Procedure

Similarly 12.1 g. of 2,3-dimethylnitrobenzene was hydrogenated to 2,3-dimethylphenylhydroxylamine, which was oxidized with ferric chloride to the nitroso compound. This compound was treated with unsymmetrical dimethylhydrazine to yield 3,3-dimethyl-1-(2,3-dimethylphenyl)triazene-1-oxide.

Sources & evidence

ORD record
ord-6d7e241275374f16bad793a338f5c42c
Source dataset
uspto-grants-1976_11
Patent number
US03989680

Reaction notes

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