4-Methylbenzaldehyde → HCID 12801389, compound

HRID 1731207Notes

Reaction equation

HRID 1731207 reaction equation
[C:1]1([CH3:9])[CH:6]=[CH:5][C:4]([CH:7]=[O:8])=[CH:3][CH:2]=1.S(=O)(O)[O-].[Na+].[N+:15]([CH2:18][CH2:19][CH3:20])([O-:17])=[O:16].[OH-].[Na+]>C(O)C.O>[N+:15]([CH:18]([CH2:19][CH3:20])[CH:7]([C:4]1[CH:5]=[CH:6][C:1]([CH3:9])=[CH:2][CH:3]=1)[OH:8])([O-:17])=[O:16]

Participants

7

Reactant 4

HCID 77254-MethylbenzaldehydeHCID 79031-NitropropaneHCID 14798Sodium HydroxideHCID 23665763Sodium Bisulfite

Product 1

HCID 12801389HCID 12801389, compound

Reagents, catalysts & solvents 2

HCID 702EthanolSolventHCID 962WaterSolvent

Procedure

The procedure of Example 1 was followed for the reaction of 120 g of p-tolualdehyde and 114 g of sodium bisulfite with 178 g of 1-nitropropane and 80 g of sodium hydroxide. Water and ethanol were the solvents. The product obtained was a clear, yellow liquid weighing 100 g; ir (film) 2.8 (s), 3.4 (m), 6.5 (s), 7.3 (m), 9.7 (m), 12.2 (s) microns.

Workup

  1. customThe product obtained

Sources & evidence

ORD record
ord-f0710b8b8ae84a01b59236e99ac37ff5
Source dataset
uspto-grants-1976_11
Patent number
US03995063

Reaction notes

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