Triethylamine → HCID 86741099, compound

HRID 1731483Notes

Reaction equation

HRID 1731483 reaction equation
[N+]([O-])([O-])=O.[Ag+:5].C(N(CC)CC)C.[NH2:13][C:14]1[C:27]2[C:26](=[O:28])[C:25]3[C:20](=[CH:21][CH:22]=[CH:23][CH:24]=3)[C:19](=[O:29])[C:18]=2[C:17]([NH2:30])=[CH:16][CH:15]=1>C(#N)C>[Ag:5].[NH2:13][C:14]1[C:27]2[C:26](=[O:28])[C:25]3[C:20](=[CH:21][CH:22]=[CH:23][CH:24]=3)[C:19](=[O:29])[C:18]=2[C:17]([NH2:30])=[CH:16][CH:15]=1

Participants

5

Reactant 3

HCID 8471TriethylamineHCID 24470Silver NitrateHCID 31420Disperse Violet 1

Product 1

HCID 86741099HCID 86741099, compound

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

Silver (I) nitrate (0.71g) is dissolved in acetonitrile (25 ml). Triethylamine (0.3 ml) and 1,4-diamino anthraquinone (0.5 g) are added and a precipitate forms immediately. The precipitate is collected and washed with acetonitrile, dimethylformamide, acetonitrile, and finally methylene chloride before drying. The yield is 0.22 g of a dark blue-black powder having a conductivity of 7.9×10-3S/cm. Analysis shows a composition of C--38.6 percent, H--2.06 percent, N--6.12 percent and Ag--40.1 percent.

Workup

  1. customThe precipitate is collected
  2. washwashed with acetonitrile, dimethylformamide, acetonitrile, and finally methylene chloride
  3. custombefore drying

Sources & evidence

ORD record
ord-5b2c75ac6b784338bcdcf36cfebaccaa
Source dataset
uspto-grants-1986_11
Patent number
US04622169

Reaction notes

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