Acridine → HCID 178420595, compound

HRID 1739341Notes

Reaction equation

HRID 1739341 reaction equation
[Cl-].[Cl-].[CH-:3]1[CH:7]=[CH:6][CH:5]=[CH:4]1.[CH-:8]1[CH:12]=[CH:11][CH:10]=[CH:9]1.[Zr+2:13].[CH:14]1[C:27]2[C:18](=[N:19][C:20]3[C:25]([CH:26]=2)=[CH:24][CH:23]=[CH:22][CH:21]=3)[CH:17]=[CH:16][CH:15]=1.[Mg]>C1COCC1>[CH:14]1[C:27]2[C:18](=[N:19][C:20]3[C:25]([CH:26]=2)=[CH:24][CH:23]=[CH:22][CH:21]=3)[CH:17]=[CH:16][CH:15]=1.[CH:3]1([Zr:13][CH:8]2[CH:12]=[CH:11][CH:10]=[CH:9]2)[CH:7]=[CH:6][CH:5]=[CH:4]1

Participants

5

Reactant 3

HCID 9215AcridineHCID 5462224MagnesiumHCID 131716798Zirconocene dichioride

Product 1

HCID 178420595HCID 178420595, compoundYield 62.6%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

To a solution of 5.00 g (17.10 mmol) zirconocene dichloride in 100 ml THF were added 3.06 g (17.10 mmol) acridine and 0.41 g magnesium and the mixture was stirred at room temperature until the metal was fully reacted. The solvent was then removed to dryness in vacuo and the residue was extracted with 80 ml toluene. 4.29 g bis(cyclopentadienyl)zirconium acridine were isolated from the toluene extract as a red solid.

Workup

  1. customwas fully reacted
  2. customThe solvent was then removed to dryness in vacuo
  3. extractionthe residue was extracted with 80 ml toluene

Sources & evidence

ORD record
ord-1d54165475314d3dbb42778b2e660b2f
Source dataset
uspto-grants-1999_10
Patent number
US05965678

Reaction notes

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