Hydroxylamine → 3-Nitrobenzaldoxime

HRID 1740804Notes

Reaction equation

HRID 1740804 reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:9]=[CH:10][CH:11]=1)[CH:7]=O)([O-:3])=[O:2].[NH2:12][OH:13]>[OH-].[Na+]>[N+:1]([C:4]1[CH:5]=[C:6]([CH:9]=[CH:10][CH:11]=1)[CH:7]=[N:12][OH:13])([O-:3])=[O:2]

Participants

4

Reactant 2

HCID 787HydroxylamineHCID 74493-Nitrobenzaldehyde

Product 1

HCID 2191323-NitrobenzaldoximeYield 79%

Reagents, catalysts & solvents 1

HCID 14798Sodium HydroxideSolvent

Procedure

3-Nitrobenzaldehyde (6 g, 40 mmol) was added to a solution of hydroxylamine (15 g, 216 mmol) in 5% aqueous sodium hydroxide solution (120 ml). Filtration and drying afforded the title compound as a white solid (5.23 g, 79%).

Workup

  1. filtrationFiltration
  2. customdrying

Sources & evidence

ORD record
ord-7aa9eb363d12436c821bd3bfd0e50c0b
Source dataset
uspto-grants-1999_10
Patent number
US05972937

Reaction notes

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