Boron trifluoride → HCID 20510464, compound

HRID 1758027Notes

Reaction equation

HRID 1758027 reaction equation
[C:1]([OH:16])(=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14].[CH3:17][C:18]1[CH:24]=[C:23]([OH:25])[CH:22]=[CH:21][C:19]=1[OH:20].B(F)(F)F.C(=O)([O-])[O-].[Na+].[Na+]>O>[CH3:17][C:18]1[CH:24]=[C:23]([C:22]([C:1](=[O:16])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])=[CH:21][C:19]=1[OH:20])[OH:25]

Participants

6

Reactant 4

HCID 6356Boron trifluorideHCID 7253MethylhydroquinoneHCID 10340Sodium CarbonateHCID 11005Myristic Acid

Product 1

HCID 20510464HCID 20510464, compound

Reagents, catalysts & solvents 1

HCID 962WaterSolvent2×

Conditions

Temperature
100 °C

Procedure

228 g (1 mole) of myristic acid and 136 g (1.1 mole) of monomethylhydroquinone were melted together whilst stirring a 100° C. and saturated with boron trifluoride for 4 h. After being stirred for 2 h at 100° C. the mixture was poured into 3 l of water. The product formed was pulverized under water and neutralized with a solution of 110 g of sodium carbonate in 400 ml of water, suction-filtered, washed with water, dried, and recrystallized from benzine. Yield: 305 g of compound Y1a. Melting point: 83° C.

Workup

  1. customThe product formed
  2. filtrationsuction-filtered
  3. washwashed with water
  4. customdried
  5. customrecrystallized from benzine

Sources & evidence

ORD record
ord-db6aa7e6f24b4b88bae30000986af1d1
Source dataset
uspto-grants-1983_02
Patent number
US04371604

Reaction notes

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