Nitromethane → HCID 69532064, compound

HRID 1760896Notes

Reaction equation

HRID 1760896 reaction equation
[CH2:1]([O:13][C:14]1[CH:21]=[CH:20][C:17]([CH:18]=O)=[CH:16][C:15]=1[O:22][CH3:23])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].C([O-])(=O)C.[NH4+].[N+:29]([CH3:32])([O-:31])=[O:30]>CO>[N+:29]([CH:32]=[CH:18][C:17]1[CH:20]=[CH:21][C:14]([O:13][CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])=[C:15]([O:22][CH3:23])[CH:16]=1)([O-:31])=[O:30]

Participants

5

Reactant 3

HCID 6375NitromethaneHCID 2875324-(dodecyloxy)-3-methoxybenzaldehydeHCID 517165Ammonium Acetate

Product 1

HCID 69532064HCID 69532064, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

4-Dodecyloxy-3-methoxybenzaldehyde (166 g; 0.519 mol) is heated for 2 hours at 100° C. with ammonium acetate (20 g; 0.388 mol) and nitromethane (49 ml; 0.914 mol). The resulting melt is then added dropwise with vigorous stirring to methanol, yellow crystals precipitating. After filtration, the residue is washed several times with methanol and then dried.

Workup

  1. additionThe resulting melt is then added dropwise
  2. customprecipitating
  3. filtrationAfter filtration
  4. washthe residue is washed several times with methanol
  5. customdried

Sources & evidence

ORD record
ord-81516bae352b4699a83761da706d07a4
Source dataset
uspto-grants-2005_01
Patent number
US06846492B2

Reaction notes

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