Methacrylamide → Allyl methacrylate

HRID 1761955Notes

Reaction equation

HRID 1761955 reaction equation
C(N)(=O)C(C)=C.[Na].C(OC)(=O)C(C)=C.[C:15]([O:20][CH2:21][CH:22]1O[CH2:23]1)(=[O:19])[C:16]([CH3:18])=[CH2:17].C(OCCOC(=O)C(C)=C)(=O)C(C)=C>O>[C:15]([O:20][CH2:21][CH:22]=[CH2:23])(=[O:19])[C:16]([CH3:18])=[CH2:17]

Participants

7

Reactant 5

HCID 6595MethacrylamideHCID 6658Methyl MethacrylateHCID 7355Ethylene glycol dimethacrylateHCID 7837Glycidyl methacrylateHCID 5360545Sodium

Product 1

HCID 7274Allyl methacrylate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
80 °C

Procedure

Subsequently, over a period of 90 minutes, the following are added simultaneously: a solution of 20 g of methacrylamide and 0.6 g of the sodium salt of 4,4'-azobis-(4-cyanovalerianic acid) in 300 g of water, as well as a monomer mixture comprising 35 g of methyl methacrylate, 40 g of glycidyl methacrylate, and 4 g of ethylene glycol dimethacrylate. The mixture is then stirred for a further 60 minutes at 80° C.

Workup

  1. additionthe following are added simultaneously

Sources & evidence

ORD record
ord-5f804b325f9849abb3dbfa8f04cc7696
Source dataset
uspto-grants-1989_05
Patent number
US04829101

Reaction notes

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