HCID 22042415, compound → HCID 22042443, compound

HRID 1790888Notes

Reaction equation

HRID 1790888 reaction equation
[CH:1]([C:3]1([C:6]2([CH3:11])[O:10][CH2:9][CH2:8][O:7]2)[CH2:5][CH2:4]1)=[CH2:2].[H][H]>C(OCC)(=O)C.[Pt](=O)=O>[CH2:1]([C:3]1([C:6]2([CH3:11])[O:7][CH2:8][CH2:9][O:10]2)[CH2:4][CH2:5]1)[CH3:2]

Participants

5

Reactant 2

HCID 22042415HCID 22042415, compoundHCID 178418361HCID 178418361, compound

Product 1

HCID 22042443HCID 22042443, compoundYield 78.6%

Reagents, catalysts & solvents 2

HCID 345198Adams' catalystCatalystHCID 8857Ethyl AcetateSolvent

Procedure

500 mg of olefin 8 is dissolved in 15 ml of ethyl acetate, 150 mg of platinum(IV) oxide is added and hydrogenated in a hydrogenating apparatus until no more hydrogen is taken up. After filtration, it is concentrated by evaporation, whereby 398 mg of title compound 195 is obtained as a colorless oil, which is immediately further reacted.

Workup

  1. filtrationAfter filtration, it
  2. concentrationis concentrated by evaporation

Sources & evidence

ORD record
ord-8f2172af70fa4b9d89d9973bf5fff44b
Source dataset
uspto-grants-2006_07
Patent number
US07071344B1

Reaction notes

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