HRID179645

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID312

Chloride

Cl-

HCID313

Hydrochloric Acid

ClH

HCID8028

Tetrahydrofuran

C4H8O

HCID19220

1-Benzyl-4-piperidone

C12H15NO

结构：c1ccc(C[P+](c2ccccc2)(c2ccccc2)c2ccccc2)cc1

HCID70672

Benzyltriphenylphosphonium

C25H22P+

HCID10773559

4-benzylidene-piperidine

C12H15N

HCID178418339

未命名化合物

PRODUCTS

生成物

HCID21843364

1-(Phenylmethyl)-4-(phenylmethylene)piperidine

C19H21N

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-4ebe227d26364216986609b203e0cc61
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (6/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (6/10)

反应 SMILES

[CH2:20]([c:21]1[cH:22][cH:23][cH:24][cH:25][cH:26]1)[N:27]1[CH2:28][CH2:29][C:30](=[O:31])[CH2:32][CH2:33]1.[CH2:35]([P+:36]([c:37]1[cH:38][cH:39][cH:40][cH:41][cH:42]1)([c:43]1[cH:44][cH:45][cH:46][cH:47][cH:48]1)[c:49]1[cH:50][cH:51][cH:52][cH:53][cH:54]1)[c:55]1[cH:56][cH:57][cH:58][cH:59][cH:60]1.[CH:2]([c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1)=[C:9]1[CH2:10][CH2:11][NH:12][CH2:13][CH2:14]1.[Cl-:34].[ClH:1].[Li:15][CH2:16][CH2:17][CH2:18][CH3:19].[O:61]1[CH2:62][CH2:63][CH2:64][CH2:65]1>>[CH:2]([c:3]1[cH:4][cH:5][cH:6][cH:7][cH:8]1)=[C:9]1[CH2:10][CH2:11][N:12]([CH2:20][c:21]2[cH:22][cH:23][cH:24][cH:25][cH:26]2)[CH2:13][CH2:14]1