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HRID1822496

反应详情

EQUATION

反应方程式

HRID 1822496 的结构方程式

REACTANTS

反应物

2
结构：O=Cc1ccc([N+](=O)[O-])cc1
HCID541

4-Nitrobenzaldehyde

C7H5NO3

结构：CCSC(=O)C(OCc1ccccc1)C(=O)O
HCID178477513

未命名化合物

PRODUCTS

生成物

1
结构：CCSC(=O)/C(=C/c1ccc([N+](=O)[O-])cc1)OCc1ccccc1
HCID178477495

未命名化合物

收率 81%

AUXILIARIES

试剂、催化剂与溶剂

3
结构：CN(C)c1ccncc1
试剂HCID14284

N,N-Dimethylpyridin-4-amine

C7H10N2

结构：NCc1ccccc1.O=C(O)C(F)(F)F
催化剂HCID12484433

Trifluoroacetic acid--1-phenylmethanamine (1/1)

C9H10F3NO2

结构：CN(C)C=O
溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

CONDITIONS

反应条件

温度
50 °C

WORKUP

后处理

  1. temperatureThe product mixture was cooled to 25 °C.
  2. filtrationFiltered through a pad of celite · 保留 Organic
  3. wash"The celite was washed with ethyl acetate (3 x 1 mL)."
  4. concentrationThe filtrate was concentrated under reduced pressure
  5. additionA 0.07 M stock solution of the internal standard ethylene carbonate (0.70 mL in CDCl3) was added.