Acetic Acid → HCID 15711941, compound

HRID 1834437Notes

Reaction equation

HRID 1834437 reaction equation
[CH3:1][C:2]1[NH:3][C:4]([CH3:7])=[CH:5][CH:6]=1.I.[PH2](O)=O.[CH3:12][CH:13]1OC(C)OC(C)O1.[C:21](O)(=O)[CH3:22]>>[CH3:1][C:2]1[NH:3][C:4]([CH3:7])=[C:5]([CH2:21][CH3:22])[C:6]=1[CH2:12][CH3:13]

Participants

6

Reactant 5

HCID 176Acetic AcidHCID 122652,5-DimethylpyrroleHCID 24841Hydrogen iodideHCID 31264ParaldehydeHCID 4124402Phosphinic Acid

Product 1

HCID 15711941HCID 15711941, compound

Procedure

As in Example 58, using 2,5-dimethyl-pyrrole (2g), acetic acid (50 ml), hydriodic acid (50 ml), hypophosphorous acid (10 ml) and paraldehyde (1.4 ml). The product (46%) was an oil, b.p. 48°-50° (0.05 mm). Anal. Calc. for C10H17N: C, 79.40; H, 11.34; N, 9.26. Found: C, 79.21; H, 11.53; N, 9.09.

Sources & evidence

ORD record
ord-0067c9bf44184956892ac67a7291b5a9
Source dataset
uspto-grants-1978_01
Patent number
US04070366

Reaction notes

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