Hydroquinone → tert-Butyl peroxybenzoate

HRID 1858054Notes

Reaction equation

HRID 1858054 reaction equation
C[O-].[Na+].[O-2].[Al+3].[O-2].[O-2].[Al+3].C1(C=CC(O)=CC=1)[OH:10].CCC(OOC(OO)(CC)C)(OO)C.CN(C)C1C=CC=CC=1.[C:40]([O:49][O:50][C:51]([C:54]1[CH:59]=[CH:58][CH:57]=[CH:56][CH:55]=1)(C)C)([C:43]1C=CC=CC=1)([CH3:42])[CH3:41].C(OCCOCCOC(=O)C=C)(=O)C=C>ClCCl.C1(C)C=CC=CC=1>[C:40]([O:49][O:50][C:51](=[O:10])[C:54]1[CH:59]=[CH:58][CH:57]=[CH:56][CH:55]=1)([CH3:43])([CH3:42])[CH3:41]

Participants

10

Reactant 7

HCID 785HydroquinoneHCID 949N,N-DimethylanilineHCID 6641Dicumyl peroxideHCID 19996Diethylene glycol diacrylateHCID 3672772Methyl ethyl ketone peroxideHCID 9989226AluminaHCID 10942334Sodium Methoxide

Product 1

HCID 11966tert-Butyl peroxybenzoate

Reagents, catalysts & solvents 2

HCID 1140TolueneSolventHCID 6344DichloromethaneSolvent

Procedure

Sodium methoxide (NaOCH3), toluene (anhydrous), dichloromethane, hexanes, activated neutral aluminum oxide (60 to 50 mesh), hydroquinone, methyl ethyl ketone peroxide, dimethylaniline, dicumylperoxide, diethylene glycol diacrylate, and tert-butylperoxybenzoate were obtained from commercial sources and used as received.

Sources & evidence

ORD record
ord-1b265212be2f48a2b206a49a2742bb59
Source dataset
uspto-grants-2000_11
Patent number
US06150429

Reaction notes

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