Ammonium → Methyl 4-amino-6-bromo-3-chloropicolinate

HRID 186588Notes

Reaction equation

HRID 186588 reaction equation
[Al+3:2].[Br:7][c:8]1[cH:9][c:10]([N+:19]([O-:20])=[O:21])[c:11]([Cl:18])[c:12]([C:14](=[O:15])[O:16][CH3:17])[n:13]1.[Cl-:30].[Cl-:31].[Cl-:32].[Cl-:33].[H-:1].[H-:4].[H-:5].[H-:6].[Li+:3].[NH4+:24].[O:25]1[CH2:26][CH2:27][CH2:28][CH2:29]1.[OH-:23].[OH2:22].[Ti+4:34]>>[Br:7][c:8]1[cH:9][c:10]([NH2:19])[c:11]([Cl:18])[c:12]([C:14](=[O:15])[O:16][CH3:17])[n:13]1

Participants

11

Reactant 10

HCID 223AmmoniumHCID 312Chloride4×HCID 961HydroxideHCID 962WaterHCID 8028TetrahydrofuranHCID 28486Lithium ionHCID 104727Aluminum CationHCID 114942Titanium cation (4+)HCID 166653Hydride4×HCID 21696610HCID 21696610, compound

Product 1

HCID 22677536Methyl 4-amino-6-bromo-3-chloropicolinate

Sources & evidence

ORD record
ord-037a0a4de8d74bd99f3b667ffce939df
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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