Bicarbonate Ion → 3-(2,4-Bis{[2-(trimethylsilyl)ethoxy]methoxy}phenyl)-4-(bromomethyl)-7-{[2-(trimethylsilyl)ethoxy]methoxy}-2H-1-benzopyran-2-one
Reaction equation
[Br:51][Br:52].[CH2:1]([Li:2])[CH2:3][CH2:4][CH3:5].[CH2:70]1[O:71][CH2:72][CH2:73][CH2:74]1.[CH3:64][CH2:65][CH2:66][CH2:67][CH2:68][CH3:69].[CH3:6][Si:7]([CH2:8][CH2:9][O:10][CH2:11][O:12][c:13]1[c:14](-[c:28]2[c:29](=[O:48])[o:30][c:31]3[cH:32][c:33]([O:39][CH2:40][O:41][CH2:42][CH2:43][Si:44]([CH3:45])([CH3:46])[CH3:47])[cH:34][cH:35][c:36]3[c:37]2[CH3:38])[cH:15][cH:16][c:17]([O:19][CH2:20][O:21][CH2:22][CH2:23][Si:24]([CH3:25])([CH3:26])[CH3:27])[cH:18]1)([CH3:49])[CH3:50].[CH3:75][CH2:76][O:77][C:78]([CH3:79])=[O:80].[Na+:57].[Na+:62].[Na+:63].[O-:53][C:54]([OH:55])=[O:56].[S:58]([O-:59])([O-:60])=[O:61]>>[CH3:6][Si:7]([CH2:8][CH2:9][O:10][CH2:11][O:12][c:13]1[c:14](-[c:28]2[c:29](=[O:48])[o:30][c:31]3[cH:32][c:33]([O:39][CH2:40][O:41][CH2:42][CH2:43][Si:44]([CH3:45])([CH3:46])[CH3:47])[cH:34][cH:35][c:36]3[c:37]2[CH2:38][Br:51])[cH:15][cH:16][c:17]([O:19][CH2:20][O:21][CH2:22][CH2:23][Si:24]([CH3:25])([CH3:26])[CH3:27])[cH:18]1)([CH3:49])[CH3:50]Participants
10
Reactant 9
Product 1
Sources & evidence
- ORD record
- ord-055da586a71846e5b08efb7883bc040a
- Source dataset
- Training data from https://doi.org/10.1039/C8SC04228D (6/10)
Reaction notes
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