Fluorosulfuric acid → HCID 86644015, compound

HRID 1889207Notes

Reaction equation

HRID 1889207 reaction equation
[F:1][S:2]([OH:5])(=[O:4])=[O:3].[CH:6]1([P:12]([CH:19]2[CH2:24][CH2:23][CH2:22][CH2:21][CH2:20]2)[CH:13]2[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]2)[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1>C(OCC)C>[F:1][S:2]([O-:5])(=[O:4])=[O:3].[CH:19]1([PH+:12]([CH:6]2[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11]2)[CH:13]2[CH2:18][CH2:17][CH2:16][CH2:15][CH2:14]2)[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24]1

Participants

4

Reactant 2

HCID 24603Fluorosulfuric acidHCID 75806Tricyclohexylphosphine

Product 1

HCID 86644015HCID 86644015, compoundYield 105.1%

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

0.7 ml (12 mmol) fluorosulfonic acid is added to 25 ml of a solution of 12 mmol tricyclohexyl phosphine in diethylether prepared as in example 2. The product precipitates with a strong exotherm. 4.8 g of a colorless solid is obtained.

Workup

  1. customThe product precipitates with a strong exotherm

Sources & evidence

ORD record
ord-00439bd6162e462b8174b336196f289f
Source dataset
uspto-grants-2013_08
Patent number
US08501985B2

Reaction notes

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