Benzoic Acid → Benzoic Acid

HRID 1912247Notes

Reaction equation

HRID 1912247 reaction equation
[C:1]([OH:9])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.C(#N)C.[Ag:13]=O>COC(C)(C)C>[Ag:13].[C:1]([OH:9])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

6

Reactant 3

HCID 243Benzoic AcidHCID 6342AcetonitrileHCID 92152Silver(II) oxide

Product 2

HCID 243Benzoic AcidHCID 23954Silver

Reagents, catalysts & solvents 1

HCID 15413tert-Butyl methyl etherSolvent

Conditions

Temperature
23 °C

Procedure

A mixture of 2.54 parts of benzoic acid and 12.00 parts of acetonitrile was stirred at 23° C. for 30 minutes. To the resultant mixture, 2.32 parts of silver oxide was added and then, the resultant mixture was stirred at 23° C. for 4 hours followed by filtration. The solid obtained was mixed with 10 parts of tert-butyl methyl ether and the resultant mixture was stirred at 23° C. for 30 minutes followed by filtration. The solid obtained was dried to obtain 3.19 parts of silver salt of benzoic acid.

Workup

  1. filtrationfollowed by filtration
  2. customThe solid obtained
  3. filtrationfollowed by filtration
  4. customThe solid obtained
  5. customwas dried

Sources & evidence

ORD record
ord-8db13036c2934fe988a520c2c7e66c13
Source dataset
uspto-grants-2013_12
Patent number
US08609317B2

Reaction notes

Loading…