Phenylacetaldehyde → HCID 12385029, compound

HRID 1941472Notes

Reaction equation

HRID 1941472 reaction equation
[C:1]1([CH2:7][CH:8]=[O:9])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.CSC>>[C:1]1([CH2:7][CH:8]2[O:9][CH:7]2[C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 2

HCID 998PhenylacetaldehydeHCID 1068Dimethyl Sulfide

Product 1

HCID 12385029HCID 12385029, compoundYield 80%

Procedure

Using the method of Example 36 with phenylacetaldehyde but using (1 mmol) of dimethyl sulfide gave the title compound in 80% yield as a clear oil. δH (CDCl3, 250 MHz): 7.3-7.1 (10H,m), 3.55 (1H,d,J=2.0 Hz), 3.05 (1H, dt,J=6.0 Hz,J=2.0 Hz), 2.80 (2H,d,J=6.0 Hz)ppm.

Sources & evidence

ORD record
ord-f1f4dac020bc47ffbc0f4f6c65550c5b
Source dataset
uspto-grants-1997_12
Patent number
US05703246

Reaction notes

Loading…