Salicylic Acid → HCID 140546754, compound

HRID 1950698Notes

Reaction equation

HRID 1950698 reaction equation
[OH:1][C:2]1[CH:10]=[CH:9][C:8]([CH:11]([CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25])[CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])=[CH:7][C:3]=1[C:4]([OH:6])=[O:5].C(O)(=O)C1C(=CC=CC=1)O.C1(C)C(C)=CC=CC=1.[OH-].[Ca+2:45].[OH-]>O.CO>[CH3:16][CH2:15][CH2:14][CH2:13][CH2:12][CH:11]([C:8]1[CH:7]=[C:3]([C:4]([O-:6])=[O:5])[C:2]([OH:1])=[CH:10][CH:9]=1)[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25].[Ca+2:45].[CH3:16][CH2:15][CH2:14][CH2:13][CH2:12][CH:11]([C:8]1[CH:7]=[C:3]([C:4]([O-:6])=[O:5])[C:2]([OH:1])=[CH:10][CH:9]=1)[CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH3:25]

Participants

7

Reactant 4

HCID 338Salicylic AcidHCID 7237O-XyleneHCID 6093208Calcium HydroxideHCID 68551883HCID 68551883, compound

Product 1

HCID 140546754HCID 140546754, compound

Reagents, catalysts & solvents 2

HCID 887MethanolSolventHCID 962WaterSolvent

Procedure

The title compound in 4 g of base oil XOMAPE 150 (13.2 g, Basicity Index 1.48) was prepared as outlined in Example 4 by employing 5-(pentadecy-6-yl)salicylic acid (Example 15, 3.3 g), a commercial lower alkyl (i.e. less than C20) salicylic acid (Infineum M7103, obtainable from Infineum UK Limited, 3.70 g), xylene (203 g), calcium hydroxide (4 g), and a promoter (methanol:water (97%:3%), 23.4 ml).

Sources & evidence

ORD record
ord-5de8201cd4654d468eb5be8d406ed0f4
Source dataset
uspto-grants-2013_03
Patent number
US08404627B2

Reaction notes

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