Methyl Acrylate → HCID 18533163, compound

HRID 1953809Notes

Reaction equation

HRID 1953809 reaction equation
[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([SH:9])=[CH:5][CH:4]=1.[C:10]([O:14][CH3:15])(=[O:13])[CH:11]=[CH2:12].C(=O)([O-])[O-].[K+].[K+]>ClCCl>[CH3:1][O:2][C:3]1[CH:8]=[CH:7][C:6]([S:9][CH2:12][CH2:11][C:10]([O:14][CH3:15])=[O:13])=[CH:5][CH:4]=1

Participants

5

Reactant 3

HCID 7294Methyl AcrylateHCID 11430Potassium CarbonateHCID 127654-Methoxybenzenethiol

Product 1

HCID 18533163HCID 18533163, compoundYield 100%

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

4-Methoxythiophenol (4.80 g) was added to a stirred solution of methyl acrylate (3.08 ml) in dichloromethane (60 ml) at 0° C. Potassium carbonate (4.72 g) was added and the mixture was allowed to warm to room temperature overnight. The mixture was filtered over a plug of Celite® and the solvent was removed in vacuo to give the title compound as a yellow liquid (7.70 g, 100%).

Workup

  1. filtrationThe mixture was filtered over a plug of Celite®
  2. customthe solvent was removed in vacuo

Sources & evidence

ORD record
ord-c555bad20252496eb4371bd3a2d2cab6
Source dataset
uspto-grants-2000_09
Patent number
US06118001

Reaction notes

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