3-Hydroxy-10,13-dimethyl-1,2,3,4,7,8,9,11,12,14,15,16-dodecahydrocyclopenta(a)phenanthren-17-one → Dehydroepiandrosterone, (E)-, TBDMS derivative
Reaction equation
[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([CH3:6])([CH3:7])[Cl:8].[CH3:38][N:39]([CH3:40])[c:41]1[cH:42][cH:43][n:44][cH:45][cH:46]1.[CH3:9][CH2:10][N:11]([CH2:12][CH3:13])[CH2:14][CH3:15].[CH:16]12[CH2:17][CH:18]=[C:19]3[CH2:20][CH:21]([OH:22])[CH2:23][CH2:24][C:25]3([CH3:26])[CH:27]1[CH2:28][CH2:29][C:30]1([CH3:31])[C:32](=[O:33])[CH2:34][CH2:35][CH:36]21.[O:47]=[CH:48][N:49]([CH3:50])[CH3:51].[OH2:37]>>[C:1]([CH3:2])([CH3:3])([CH3:4])[Si:5]([CH3:6])([CH3:7])[O:22][CH:21]1[CH2:20][C:19]2=[CH:18][CH2:17][CH:16]3[CH:27]([C:25]2([CH3:26])[CH2:24][CH2:23]1)[CH2:28][CH2:29][C:30]1([CH3:31])[C:32](=[O:33])[CH2:34][CH2:35][CH:36]31Participants
7
Reactant 6
Product 1
Sources & evidence
- ORD record
- ord-d06d746353734f958458707d302056d7
- Source dataset
- Training data from https://doi.org/10.1039/C8SC04228D (6/10)
Reaction notes
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