HRID1960234

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID944

Nitric Acid

HNO3

HCID8217

1-Octadecene

C18H36

HCID11005

Tetradecanoic acid

C14H28O2

HCID11635

Octadecane

C18H38

HCID14798

Sodium Hydroxide

HNaO

$结构：CCCCCCCC/C=C\CCCCCCCC(=O)O$

HCID445639

Oleic acid

C18H34O2

HCID5362487

Sulfur

结构：O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Cd+2]

HCID56924536

Cadmium nitrate tetrahydrate

H8CdN2O10

PRODUCTS

生成物

结构：CCCCCCCCCCCCCC(=O)[O-].CCCCCCCCCCCCCC(=O)[O-].[Cd+2]

HCID66290

Tetradecanoic acid, cadmium salt (2:1)

C28H54CdO4

AUXILIARIES

试剂、催化剂与溶剂

结构：CCCCCCCCCCCCCCCCCC(=O)[O-].CCCCCCCCCCCCCCCCCC(=O)[O-].[Zn+2]

催化剂HCID11178

Octadecanoic acid, zinc salt

C36H70O4Zn

催化剂HCID93021

Manganese acetate tetrahydrate

C4H14MnO8

PROCEDURE

实验过程

Sulfur powder (99.999%), oleic acid (OLA, 90%), 1-octadecene (ODE, 90%), octadecane (ODA, 99%), oleyamine (OAm, 70%), polystyrene-block-polybutadiene (C12H14, 30 wt % styrene, 80% diblock), cadmium nitrate tetrahydrate (Cd(NO3)2.4H2O, 99.99%), zinc stearate (count as ZnO %≈14%), myristic acid (MA, 99%), nitric acid (69.5%), manganese acetate tetrahydrate (99%), and sodium hydroxide (NaOH) were purchased from commercial sources and used as received without further purification. Cadmium myristate was synthesized according to a literature method.

WORKUP

后处理

customas received without further purification

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-7fa8d41e84da478380eeb966cde52733
来源数据集: uspto-grants-2013_04
DOI: 10.6084/m9.figshare.5104873.v1
专利: US08410455B2
来源说明: uspto-grants-2013_04

反应 SMILES

[S].[C:2]([OH:21])(=[O:20])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9]/[CH:10]=[CH:11]\[CH2:12][CH2:13][CH2:14][CH2:15]CCCC.C=CCCCCCCCCCCCCCCCC.CCCCCCCCCCCCCCCCCC.O.O.O.O.[N+]([O-])([O-])=O.[Cd+2:66].[N+]([O-])([O-])=O.C(O)(=O)CCCCCCCCCCCCC.[N+]([O-])(O)=O.[OH-].[Na+]>C([O-])(=O)CCCCCCCCCCCCCCCCC.[Zn+2].C([O-])(=O)CCCCCCCCCCCCCCCCC.O.O.O.O.C([O-])(=O)C.[Mn+2].C([O-])(=O)C>[C:2]([O-:21])(=[O:20])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15].[Cd+2:66].[C:2]([O-:21])(=[O:20])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]