Methane → HCID 58096311, compound

HRID 1968677Notes

Reaction equation

HRID 1968677 reaction equation
[CH3:1][N:2]([C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1)[S:3]([C:6](=O)[C:7]1C=[CH:11][C:10]([NH:13]C)=[C:9]([N+:15]([O-])=O)[CH:8]=1)(=[O:5])=[O:4].O.NN.[CH4:28]>C(O)(C)C>[NH2:13][C:10]1[CH:11]=[C:6]([S:3]([N:2]([CH3:1])[C:19]2[CH:20]=[CH:21][CH:22]=[CH:23][CH:24]=2)(=[O:4])=[O:5])[CH:7]=[CH:8][C:9]=1[NH:15][CH3:28]

Participants

5

Reactant 3

HCID 297MethaneHCID 24654Hydrazine hydrate (1:1)HCID 86649316HCID 86649316, compound

Product 1

HCID 58096311HCID 58096311, compound

Reagents, catalysts & solvents 1

HCID 3776IsopropanolSolvent

Procedure

N-Methyl-4-(methylamino)-3-nitro-N-phenylbenzoyl sulfonamide (9 g, 0.028 mol) was dissolved in isopropanol (90 ml). To this solution, hydrazine hydrate (11 ml), activated charcoal (2 g), and FeCl3.6H2O (0.5 g in 10 ml ethanol) were added. The reaction mixture was boiled for 8 h. The charcoal was removed by filtration. The filtrate was evaporated to dryness. The yield of 3-amino-N-methyl-4-(methylamino)-N-phenylbenzene sulfonamide was 8.1 g (99%).

Workup

  1. customThe charcoal was removed by filtration
  2. customThe filtrate was evaporated to dryness

Sources & evidence

ORD record
ord-3f85e27f546b4c2b9537cfe85f239187
Source dataset
uspto-grants-2013_04
Patent number
US08426433B2

Reaction notes

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