Methyl Benzoate → HCID 67530967, compound

HRID 1972110Notes

Reaction equation

HRID 1972110 reaction equation
[C:1]([O:9][CH3:10])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[NH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20]CO.C(OC(C)C)(C)C>>[C:1]([O:9][CH2:10][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][NH2:11])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

4

Reactant 3

HCID 7150Methyl BenzoateHCID 7914Diisopropyl EtherHCID 446535510-Amino-1-decanol

Product 1

HCID 67530967HCID 67530967, compoundYield 90%

Procedure

In an argon atmosphere, a mixture of methyl benzoate (3.0 mmol), 10-aminodecan-1-ol (3.6 mmol), Zn4(OCOCF3)6O (1.25 mol % in terms of mole number) and diisopropyl ether (5.0 ml) was heated to reflux for 20 hours, and as a result, 10-aminodecyl benzoate was obtained at a yield of 90%. The yield of 10-benzoylaminodecyl benzoate was 7%.

Workup

  1. temperaturewas heated
  2. temperatureto reflux for 20 hours

Sources & evidence

ORD record
ord-ebc8f457759a4503866b8bdd74650890
Source dataset
uspto-grants-2013_04
Patent number
US08431709B2

Reaction notes

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