Acrylic Acid → HCID 86602575, compound

HRID 2052753Notes

Reaction equation

HRID 2052753 reaction equation
[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[C:10]([OH:14])(=[O:13])[CH:11]=[CH2:12].[OH:15][CH2:16][CH2:17][O:18][C:19](=[O:23])[C:20]([CH3:22])=[CH2:21].CC(OC(C)=O)COC>CC(N=NC(C#N)(C)C)(C#N)C>[C:1]([O:5][C:6](=[O:9])[CH:7]=[CH2:8])([CH3:4])([CH3:3])[CH3:2].[C:10]([OH:14])(=[O:13])[CH:11]=[CH2:12].[OH:15][CH2:16][CH2:17][O:18][C:19](=[O:23])[C:20]([CH3:22])=[CH2:21]

Participants

6

Reactant 4

HCID 6581Acrylic AcidHCID 7946Propylene glycol methyl ether acetateHCID 133602-Hydroxyethyl MethacrylateHCID 15458tert-Butyl acrylate

Product 1

HCID 86602575HCID 86602575, compoundYield 210.1%

Reagents, catalysts & solvents 1

HCID 6547AzobisisobutyronitrileCatalyst

Procedure

12 g of t-butylacrylate, 5 g of acrylic acid, 3 g of 2-hydroxyethylmethacrylate and 0.4 g of AIBN were added to 200 g of PGMEA, and were then polymerized at 60° C. for 8 hours. After completion of the polymerization, the mixture was precipitated in ether, filtered, and dried in vacuo to yield 16 g of t-butylacrylate-acrylic acid-2-hydroxyethylmethacrylate copolymer, as a white solid, represented by Formula 2 below:

Workup

  1. customwere then polymerized at 60° C. for 8 hours
  2. customAfter completion of the polymerization
  3. customthe mixture was precipitated in ether
  4. filtrationfiltered
  5. customdried in vacuo

Sources & evidence

ORD record
ord-de12a85a646140a19959027baeac01d4
Source dataset
uspto-grants-2008_02
Patent number
US07326525B2

Reaction notes

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