Sodium ion → (RS)-1-(2-azido-propyl)-7-chloro-1,4-dihydro-indeno[1,2-b]-pyrrole

HRID 208219Notes

Reaction equation

HRID 208219 reaction equation
[CH3:1][S:2](=[O:3])(=[O:4])[Cl:5].[CH3:23][CH2:24][N:25]([CH2:26][CH3:27])[CH2:28][CH3:29].[CH3:37][CH2:38][O:39][CH2:40][CH3:41].[CH3:42][N:43]([CH3:44])[CH:45]=[O:46].[Cl:34][CH2:35][Cl:36].[Cl:6][c:7]1[cH:8][cH:9][c:10]2[c:21]([cH:22]1)-[c:13]1[c:12]([cH:16][cH:15][n:14]1[CH2:17][CH:18]([CH3:19])[OH:20])[CH2:11]2.[N-:31]=[N+:32]=[N-:33].[Na+:30].[OH2:47]>>[Cl:6][c:7]1[cH:8][cH:9][c:10]2[c:21]([cH:22]1)-[c:13]1[c:12]([cH:16][cH:15][n:14]1[CH2:17][CH:18]([CH3:19])[N:31]=[N+:32]=[N-:33])[CH2:11]2

Participants

10

Reactant 9

HCID 923Sodium ionHCID 962WaterHCID 3283Diethyl EtherHCID 6228DimethylformamideHCID 6344DichloromethaneHCID 8471TriethylamineHCID 31297Methanesulfonyl chlorideHCID 33558AzideHCID 19036406(RS)-1-(7-chloro-1,4-dihydro-indeno[1,2-b]pyrrol-1-yl)-propan-2-ol

Product 1

HCID 19036487(RS)-1-(2-azido-propyl)-7-chloro-1,4-dihydro-indeno[1,2-b]-pyrrole

Sources & evidence

ORD record
ord-975667d8998f47c18bdf488c7f97121f
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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