Chloride → Borane

HRID 208355Notes

Reaction equation

HRID 208355 reaction equation
[Al+3:42].[BH4-:5].[C:7]([CH3:8])([CH3:9])([CH3:10])[c:11]1[cH:12][c:13]([PH:23]([c:24]2[cH:25][c:26]([C:36]([CH3:37])([CH3:38])[CH3:39])[c:27]([O:34][CH3:35])[c:28]([C:30]([CH3:31])([CH3:32])[CH3:33])[cH:29]2)=[O:40])[cH:14][c:15]([C:19]([CH3:20])([CH3:21])[CH3:22])[c:16]1[O:17][CH3:18].[CH2:47]1[O:48][CH2:49][CH2:50][CH2:51]1.[CH3:52][c:53]1[cH:54][cH:55][cH:56][cH:57][cH:58]1.[Ce+3:2].[Cl-:1].[Cl-:3].[Cl-:4].[H-:41].[H-:44].[H-:45].[H-:46].[Li+:43].[Na+:6].[OH2:59]>>[BH3:5].[C:7]([CH3:8])([CH3:9])([CH3:10])[c:11]1[cH:12][c:13]([PH:23][c:24]2[cH:25][c:26]([C:36]([CH3:37])([CH3:38])[CH3:39])[c:27]([O:34][CH3:35])[c:28]([C:30]([CH3:31])([CH3:32])[CH3:33])[cH:29]2)[cH:14][c:15]([C:19]([CH3:20])([CH3:21])[CH3:22])[c:16]1[O:17][CH3:18]

Participants

13

Reactant 11

HCID 312Chloride3×HCID 923Sodium ionHCID 962WaterHCID 1140TolueneHCID 8028TetrahydrofuranHCID 28123BorohydrideHCID 28486Lithium ionHCID 104727Aluminum CationHCID 114853Cerium(3+)HCID 166653Hydride4×HCID 178490127HCID 178490127, compound

Product 2

HCID 6331BoraneHCID 21895223Bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphane

Sources & evidence

ORD record
ord-2ac65150aa9b4cb992074c7287f6652e
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (6/10)

Reaction notes

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