Diethyl Ether → HCID 25222139, compound

HRID 2096993Notes

Reaction equation

HRID 2096993 reaction equation
[N+:1]([C:4]1[N:9]=[C:8]2[N:10]([CH:13]([CH3:15])[CH3:14])[CH:11]=[N:12][C:7]2=[C:6]([N+:16]([O-])=O)[CH:5]=1)([O-:3])=[O:2].CCN(CC)CC.[CH2:26](N)[C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1.CCOCC>CN(C=O)C>[CH2:26]([NH:16][C:6]1[CH:5]=[C:4]([N+:1]([O-:3])=[O:2])[N:9]=[C:8]2[N:10]([CH:13]([CH3:15])[CH3:14])[CH:11]=[N:12][C:7]=12)[C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][CH:28]=1

Participants

6

Reactant 4

HCID 3283Diethyl EtherHCID 7504BenzylamineHCID 8471TriethylamineHCID 86647220HCID 86647220, compound

Product 1

HCID 25222139HCID 25222139, compound

Reagents, catalysts & solvents 1

HCID 6228DimethylformamideSolvent

Conditions

Temperature
20 °C

Procedure

To a solution of 5,7-dinitro-3-iso-propylimidazo[4,5-b]pyridine, 5, in DMF was added NEt3 and benzylamine. After 6 h stirring at 20° C., 15 mL Et2O was added and the solid which precipited was filtered and washed with Et2O.

Workup

  1. filtrationthe solid which precipited was filtered
  2. washwashed with Et2O

Sources & evidence

ORD record
ord-0d0c2e43d9de4433897f06e7b002a98e
Source dataset
uspto-grants-2013_05
Patent number
US08450342B2

Reaction notes

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