HRID2122952

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID312

Chloride

Cl-

2 次

HCID8028

Tetrahydrofuran

C4H8O

HCID32051

Zinc (II) cation

Zn+2

结构：C=C(OS(=O)(=O)C(F)(F)F)c1cccc([N+](=O)[O-])c1

HCID21877486

未命名化合物

PRODUCTS

生成物

结构：C=C(c1cccc([N+](=O)[O-])c1)c1ccc2c(C=Cc3ccccc3)nn(COCC[Si](C)(C)C)c2c1

HCID69371433

未命名化合物

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-d565a15804a34d2b9e5f8deb5f79fe7a
来源数据集: Training data from https://doi.org/10.1039/C8SC04228D (4/10)
DOI: 10.1039/C8SC04228D
来源说明: Training data from https://doi.org/10.1039/C8SC04228D (4/10)

反应 SMILES

[CH2:27]([Li:28])[CH2:29][CH2:30][CH3:31].[CH2:51]1[O:52][CH2:53][CH2:54][CH2:55]1.[Cl-:56].[Cl-:58].[I:1][c:2]1[cH:3][cH:4][c:5]2[c:6]([CH:19]=[CH:20][c:21]3[cH:22][cH:23][cH:24][cH:25][cH:26]3)[n:7][n:8]([CH2:11][O:12][CH2:13][CH2:14][Si:15]([CH3:16])([CH3:17])[CH3:18])[c:9]2[cH:10]1.[N+:32](=[O:33])([O-:34])[c:35]1[cH:36][c:37]([C:41](=[CH2:42])[O:43][S:44]([C:45]([F:46])([F:47])[F:48])(=[O:49])=[O:50])[cH:38][cH:39][cH:40]1.[Zn+2:57].[cH:59]1[cH:60][cH:61][c:62]([P:63]([Pd:64]([P:65]([c:66]2[cH:67][cH:68][cH:69][cH:70][cH:71]2)([c:72]2[cH:73][cH:74][cH:75][cH:76][cH:77]2)[c:78]2[cH:79][cH:80][cH:81][cH:82][cH:83]2)([P:84]([c:85]2[cH:86][cH:87][cH:88][cH:89][cH:90]2)([c:91]2[cH:92][cH:93][cH:94][cH:95][cH:96]2)[c:97]2[cH:98][cH:99][cH:100][cH:101][cH:102]2)[P:103]([c:104]2[cH:105][cH:106][cH:107][cH:108][cH:109]2)([c:110]2[cH:111][cH:112][cH:113][cH:114][cH:115]2)[c:116]2[cH:117][cH:118][cH:119][cH:120][cH:121]2)([c:122]2[cH:123][cH:124][cH:125][cH:126][cH:127]2)[c:128]2[cH:129][cH:130][cH:131][cH:132][cH:133]2)[cH:134][cH:135]1>>[c:2]1([C:41]([c:37]2[cH:36][c:35]([N+:32](=[O:33])[O-:34])[cH:40][cH:39][cH:38]2)=[CH2:42])[cH:3][cH:4][c:5]2[c:6]([CH:19]=[CH:20][c:21]3[cH:22][cH:23][cH:24][cH:25][cH:26]3)[n:7][n:8]([CH2:11][O:12][CH2:13][CH2:14][Si:15]([CH3:16])([CH3:17])[CH3:18])[c:9]2[cH:10]1