Acetate → 1,1-Dimethylethyl 3-(3-formylphenyl)-2-propenoate

HRID 2136281Notes

Reaction equation

HRID 2136281 reaction equation
[Br:1][c:2]1[cH:3][c:4]([CH:5]=[O:6])[cH:7][cH:8][cH:9]1.[C:10]([CH:11]=[CH2:12])(=[O:13])[O:14][C:15]([CH3:16])([CH3:17])[CH3:18].[CH3:19][CH2:20][N:21]([CH2:22][CH3:23])[CH2:24][CH3:25].[CH3:26][c:27]1[cH:28][cH:29][cH:30][cH:31][c:32]1[P:33]([c:34]1[cH:35][cH:36][cH:37][cH:38][c:39]1[CH3:40])[c:41]1[cH:42][cH:43][cH:44][cH:45][c:46]1[CH3:47].[CH3:48][N:49]([CH3:50])[CH:51]=[O:52].[O-:54][C:55]([CH3:56])=[O:57].[O-:58][C:59]([CH3:60])=[O:61].[Pd+2:53]>>[c:2]1([CH:12]=[CH:11][C:10](=[O:13])[O:14][C:15]([CH3:16])([CH3:17])[CH3:18])[cH:3][c:4]([CH:5]=[O:6])[cH:7][cH:8][cH:9]1

Participants

8

Reactant 7

HCID 175Acetate2×HCID 6228DimethylformamideHCID 8471TriethylamineHCID 15458tert-Butyl acrylateHCID 765833-BromobenzaldehydeHCID 80271Tri-o-tolylphosphineHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

Product 1

HCID 543870911,1-Dimethylethyl 3-(3-formylphenyl)-2-propenoate

Sources & evidence

ORD record
ord-4d0c7feb09b34c82adb1c1fdffdabc81
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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