Ammonium → 2-(1-Cyclopropyl-1-methylethyl)malonic acid diethyl ester

HRID 2139534Notes

Reaction equation

HRID 2139534 reaction equation
[Br-:1].[C:6]([CH3:7])([CH3:8])=[C:9]([C:10](=[O:11])[O:12][CH2:13][CH3:14])[C:15](=[O:16])[O:17][CH2:18][CH3:19].[CH:2]1([Mg+:5])[CH2:3][CH2:4]1.[Cl-:20].[Cu:27][I:28].[NH4+:21].[O:22]1[CH2:23][CH2:24][CH2:25][CH2:26]1>>[CH:2]1([C:6]([CH3:7])([CH3:8])[CH:9]([C:10](=[O:11])[O:12][CH2:13][CH3:14])[C:15](=[O:16])[O:17][CH2:18][CH3:19])[CH2:3][CH2:4]1

Participants

8

Reactant 7

HCID 223AmmoniumHCID 259Bromide ionHCID 312ChlorideHCID 8028TetrahydrofuranHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 81255Diethyl isopropylidenemalonateHCID 178507030HCID 178507030, compound

Product 1

HCID 672971112-(1-Cyclopropyl-1-methylethyl)malonic acid diethyl ester

Sources & evidence

ORD record
ord-b903510b6db4472abb7a3bd591224840
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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