Acetate → 2-CYCLOPROPYLBENZALDEHYDE

HRID 2140314Notes

Reaction equation

HRID 2140314 reaction equation
[Br:1][c:2]1[c:3]([CH:4]=[O:5])[cH:6][cH:7][cH:8][cH:9]1.[CH3:43][c:44]1[cH:45][cH:46][cH:47][cH:48][cH:49]1.[CH3:51][CH2:52][O:53][C:54](=[O:55])[CH3:56].[CH:10]1([B:13]([OH:14])[OH:15])[CH2:11][CH2:12]1.[CH:24]1([P:25]([CH:26]2[CH2:27][CH2:28][CH2:29][CH2:30][CH2:31]2)[CH:32]2[CH2:33][CH2:34][CH2:35][CH2:36][CH2:37]2)[CH2:38][CH2:39][CH2:40][CH2:41][CH2:42]1.[K+:21].[K+:22].[K+:23].[O-:58][C:59]([CH3:60])=[O:61].[O-:62][C:63]([CH3:64])=[O:65].[OH2:50].[P:16]([O-:17])([O-:18])([O-:19])=[O:20].[Pd+2:57]>>[c:2]1([CH:10]2[CH2:11][CH2:12]2)[c:3]([CH:4]=[O:5])[cH:6][cH:7][cH:8][cH:9]1

Participants

11

Reactant 10

HCID 175Acetate2×HCID 813Potassium Cation3×HCID 962WaterHCID 1061PhosphateHCID 1140TolueneHCID 8857Ethyl AcetateHCID 75806TricyclohexylphosphineHCID 811292-BromobenzaldehydeHCID 105144Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)HCID 2760897Cyclopropylboronic acid

Product 1

HCID 154733242-CYCLOPROPYLBENZALDEHYDE

Sources & evidence

ORD record
ord-586cc39bdc4143e2ae83ee7e3f9b7a95
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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