Triphenylphosphine → HCID 68934762, compound

HRID 2143926Notes

Reaction equation

HRID 2143926 reaction equation
[Br:1][c:2]1[cH:3][c:4](-[c:8]2[c:9]3[c:10]([n:11][c:12](-[c:14]4[n:15][c:16]([CH3:20])[cH:17][cH:18][cH:19]4)[n:13]2)[nH:21][cH:22][cH:23]3)[cH:5][n:6][cH:7]1.[CH3:24][Si:25]([CH3:26])([CH3:27])[C:28]#[CH:29].[Cu:30][I:31].[Pd:32]([Cl:33])[Cl:34].[c:35]1([P:36]([c:37]2[cH:38][cH:39][cH:40][cH:41][cH:42]2)[c:43]2[cH:44][cH:45][cH:46][cH:47][cH:48]2)[cH:49][cH:50][cH:51][cH:52][cH:53]1.[c:54]1([P:55]([c:56]2[cH:57][cH:58][cH:59][cH:60][cH:61]2)[c:62]2[cH:63][cH:64][cH:65][cH:66][cH:67]2)[cH:68][cH:69][cH:70][cH:71][cH:72]1>>[c:2]1([C:29]#[C:28][Si:25]([CH3:24])([CH3:26])[CH3:27])[cH:3][c:4](-[c:8]2[c:9]3[c:10]([n:11][c:12](-[c:14]4[n:15][c:16]([CH3:20])[cH:17][cH:18][cH:19]4)[n:13]2)[nH:21][cH:22][cH:23]3)[cH:5][n:6][cH:7]1

Participants

6

Reactant 5

HCID 11776Triphenylphosphine2×HCID 24290Palladium ChlorideHCID 24350Copper(1+) iodide; Copper(I) iodide; Cuprous iodide; Cuprous iodide (CuI)HCID 66111TrimethylsilylacetyleneHCID 441944484-(5-Bromo-pyridin-3-yl)-2-(6-methyl-pyridin-2-yl)-7H-pyrrolo[2,3-d]pyrimidine

Product 1

HCID 68934762HCID 68934762, compound

Sources & evidence

ORD record
ord-adaed72f5393461cb156c56329a3b074
Source dataset
Training data from https://doi.org/10.1039/C8SC04228D (4/10)

Reaction notes

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