Tin tetrachloride → HCID 89525684, compound

HRID 2205254Notes

Reaction equation

HRID 2205254 reaction equation
[CH2:1]=[C:2]([CH:4]1[CH2:9][CH2:8][CH2:7][CH2:6][C:5]1=[O:10])[CH3:3].[CH2:11]([O:13][N:14]=[CH:15][CH3:16])[CH3:12].Cl[Sn](Cl)(Cl)Cl>ClCCCl>[CH2:11]([O:13][N:14]1[CH:15]([CH3:16])[CH2:3][C:2]([CH3:1])=[CH:4][CH2:9][CH2:8][CH2:7][CH2:6][C:5]1=[O:10])[CH3:12]

Participants

5

Reactant 3

HCID 24287Tin tetrachlorideHCID 533741acetaldehyde O-ethyl oximeHCID 11018939Cyclohexanone, 2-(1-methylethenyl)-

Product 1

HCID 89525684HCID 89525684, compoundYield 80%

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

Following the general procedure as described in Example 17, 2-(prop-1-en-2-yl)cyclohexanone (0.88 g, 6.38 mmol), acetaldehyde O-ethyl oxime (0.67 g, 7.65 mmol), and SnCl4 (1.66 g, 6.38 mmol) in 1,2-dichloroethane (65 ml) were reacted to give the title product as a colorless liquid (1.14 g, 80% yield).

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-87abdc2c5c5941f78a5085e178a62adb
Source dataset
uspto-grants-2016_06
Patent number
US09371262B2

Reaction notes

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