Tin tetrachloride → HCID 131735810, compound

HRID 2205265Notes

Reaction equation

HRID 2205265 reaction equation
[CH2:1]=[C:2]([CH:4]1[CH2:9][CH2:8][CH2:7][CH2:6][C:5]1=[O:10])[CH3:3].[N:11]1[CH2:12][CH2:13][CH2:14][CH2:15][CH:16]=1.Cl[Sn](Cl)(Cl)Cl>ClCCCl>[CH3:3][C:2]1[CH2:1][CH:16]2[CH2:15][CH2:14][CH2:13][CH2:12][N:11]2[C:5](=[O:10])[CH2:6][CH2:7][CH2:8][CH2:9][CH:4]=1

Participants

5

Reactant 3

HCID 24287Tin tetrachlorideHCID 681612,3,4,5-TetrahydropyridineHCID 11018939Cyclohexanone, 2-(1-methylethenyl)-

Product 1

HCID 131735810HCID 131735810, compoundYield 69%

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

Following the general procedure as described in Example 17, 2-(prop-1-en-2-yl)cyclohexanone (0.88 g, 6.38 mmol), 2,3,4,5-tetrahydropyridine (0.64 g, 7.65 mmol), and SnCl4 (1.66 g, 6.38 mmol) in 1,2-dichloroethane (65 ml) were reacted to give the title product as a colorless liquid (0.97 g, 69% yield).

Workup

  1. customwere reacted

Sources & evidence

ORD record
ord-d4013b3d13aa4096847e396bcbe5ad89
Source dataset
uspto-grants-2016_06
Patent number
US09371262B2

Reaction notes

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