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HRID2220826

反应详情

EQUATION

反应方程式

HRID 2220826 的结构方程式

REACTANTS

反应物

3
结构：O=c1ccn([C@@H]2O[C@H](COP(=O)(O)OP(=O)(O)O)[C@@H](O)[C@H]2O)c(=O)[nH]1
HCID6031

未命名化合物

结构：CCCCN(CCCC)CCCC
HCID7622

Tributylamine

C12H27N

2 次

结构：O=c1ccn([C@@H]2O[C@H](COP(=O)([O-])OP(=O)([O-])O)[C@@H](O)[C@H]2O)c(=O)[nH]1.[Na+].[Na+]
HCID11957711

未命名化合物

PRODUCTS

生成物

2
结构：Nc1ncnc2c1ncn2[C@@H]1O[C@H](COP(=O)(O)OP(=O)(O)O)[C@@H](O)[C@H]1O
HCID6022

Adenosine diphosphate

C10H15N5O10P2

结构：O=c1ccn([C@@H]2O[C@H](COP(=O)(O)OP(=O)(O)O)[C@@H](O)[C@H]2O)c(=O)[nH]1
HCID6031

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CCO
溶剂HCID702

Ethanol

C2H6O

2 次

PROCEDURE

实验过程

ADP (Bu3NH+)2, AMP (Bu3NH+)2 and UMP (Bu3NH+)2 were prepared from the corresponding free acid and tributylamine (Bu3N; 2 eq) in EtOH. UDP (Bu3NH+)2 was prepared from UDP disodium salt. The latter salt was passed through a column of activated Dowex 50WX-8 200 mesh, H+ form. The column eluate was collected in an ice-cooled flask containing (Bu3N (2 eq) and EtOH. The resulting solution was freeze-dried to yield UDP (Bu3NH+)2 as a viscous oil.

WORKUP

后处理

  1. customThe column eluate was collected in an ice-
  2. temperaturecooled flask
  3. customThe resulting solution was freeze-dried