Hydrogen Peroxide → N,N-didodecylhydroxylamine

HRID 2231344Notes

Reaction equation

HRID 2231344 reaction equation
[CH2:1]([N:13]([CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])CCC(OC)=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[OH:32]O>C(O)(C)C>[CH2:1]([N:13]([CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH3:31])[OH:32])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 19844207HCID 19844207, compound

Product 1

HCID 9864141N,N-didodecylhydroxylamineYield 44%

Reagents, catalysts & solvents 1

HCID 3776IsopropanolSolvent

Procedure

Using the general procedure of Example 2, 87.6 grams (0.2 mol) of the product of Example 5 in 800 ml of isopropanol is oxidized using 9.7 mol (0.25 mol) of 70% aqueous hydrogen peroxide solution to give 32.1 grams (44% yield) of the above-named product as a white solid melting at 85°-86° C.

Sources & evidence

ORD record
ord-0d62064e90254e8092b4f3f82faa624c
Source dataset
uspto-grants-1988_11
Patent number
US04782105

Reaction notes

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