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HRID22316

反应详情

EQUATION

反应方程式

HRID 22316 的结构方程式

REACTANTS

反应物

4
结构：COC(C)(C)C
HCID15413

Methyl tert-butyl ether

C5H12O

结构：c1ccc(C2CCNCC2)cc1
HCID69873

4-Phenylpiperidine

C11H15N

结构：O=C([O-])/C=C/C(=O)[O-]
HCID5460307

Fumerate

C4H2O4-2

结构：CC(C)Oc1cc2ccc(=O)oc2cc1OCCCOS(C)(=O)=O
HCID19927700

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)Oc1cc2ccc(=O)oc2cc1OCCCN1CCC(c2ccccc2)CC1
HCID19927722

未命名化合物

收率 69%

AUXILIARIES

试剂、催化剂与溶剂

2
结构：CC(C)=O
溶剂HCID180

Acetone

C3H6O

结构：CCO
溶剂HCID702

Ethanol

C2H6O

PROCEDURE

实验过程

Method B (24 h at 60° C.); starting materials: 7-[3-(methanesulfonyloxy)propoxy]-6-(1-methylethoxy)-2H-1-benzopyran-2-one (example 73) and 4-phenylpiperidine; yield 69%; fusion point 86°-87° C. (from TBME). Fumarate: method E; yield 90%; fusion point 164°-167° C. (from ethanol and acetone).

WORKUP

后处理

  1. customMethod B (24 h at 60° C.)