4-Fluorobenzoic Acid → HCID 4915462, compound

HRID 2243087Notes

Reaction equation

HRID 2243087 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([NH2:10])=[C:6]([NH2:11])[CH:5]=1)([O-:3])=[O:2].[F:12][C:13]1[CH:21]=[CH:20][C:16]([C:17](O)=O)=[CH:15][CH:14]=1.[K+].[Br-]>C1(C)C=CC=CC=1.C(OCC)(=O)C>[F:12][C:13]1[CH:21]=[CH:20][C:16]([C:17]2[NH:11][C:6]3[CH:5]=[C:4]([N+:1]([O-:3])=[O:2])[CH:9]=[CH:8][C:7]=3[N:10]=2)=[CH:15][CH:14]=1

Participants

5

Reactant 3

HCID 99734-Fluorobenzoic AcidHCID 253877Potassium BromideHCID 51117914-Nitro-1,2-phenylenediamine

Product 1

HCID 4915462HCID 4915462, compoundYield 76%

Reagents, catalysts & solvents 1

HCID 21584019Toluene ethylacetateSolvent

Procedure

Prepared from 4-nitrophenylenediamine and 4-fluorobenzoic acid, in a manner similar to that of Example 9b. Yield: 76%; Rf (7/3 toluene/ethyl acetate): 0.54; IR (KBr): 3312, 1601, 1498, 1333 cm−1.

Sources & evidence

ORD record
ord-79abb47bae534c988bd4aac37d2abb88
Source dataset
uspto-grants-2010_03
Patent number
US07674809B2

Reaction notes

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