2-Methoxybenzoic acid → HCID 23085767, compound

HRID 2243101Notes

Reaction equation

HRID 2243101 reaction equation
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([NH2:10])=[C:6]([NH2:11])[CH:5]=1)([O-:3])=[O:2].[CH3:12][O:13][C:14]1[CH:22]=[CH:21][CH:20]=[CH:19][C:15]=1[C:16](O)=O.[K+].[Br-]>C1(C)C=CC=CC=1.C(OCC)(=O)C>[CH3:12][O:13][C:14]1[CH:22]=[CH:21][CH:20]=[CH:19][C:15]=1[C:16]1[NH:11][C:6]2[CH:5]=[C:4]([N+:1]([O-:3])=[O:2])[CH:9]=[CH:8][C:7]=2[N:10]=1

Participants

5

Reactant 3

HCID 113702-Methoxybenzoic acidHCID 253877Potassium BromideHCID 51117914-Nitro-1,2-phenylenediamine

Product 1

HCID 23085767HCID 23085767, compoundYield 76%

Reagents, catalysts & solvents 1

HCID 21584019Toluene ethylacetateSolvent

Procedure

Prepared from 4-nitrophenylenediamine and 2-methoxybenzoic acid, in a manner similar to that of Example 9b. Yield: 76%; Rf (6/4 toluene/ethyl acetate): 0.43; IR (KBr): 3005, 1515, 1335, 750 cm−1.

Sources & evidence

ORD record
ord-effde357019d458bb21acff2e28d5e50
Source dataset
uspto-grants-2010_03
Patent number
US07674809B2

Reaction notes

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