Cyclopentadiene → HCID 12663824, compound

HRID 224546Notes

Reaction equation

HRID 224546 reaction equation
[Na].[CH:2]1[CH2:6][CH:5]=[CH:4][CH:3]=1.Br[CH2:8][C:9]([O:11][CH3:12])=[O:10]>O1CCCC1>[CH3:12][O:11][C:9](=[O:10])[CH2:8][CH:3]1[CH:2]=[CH:6][CH:5]=[CH:4]1

Participants

5

Reactant 3

HCID 7612CyclopentadieneHCID 60984Methyl bromoacetateHCID 5360545Sodium

Product 1

HCID 12663824HCID 12663824, compound

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Procedure

2,4-Cyclopentadienyl acetic acid methyl ester was prepared from the sodium salt of cyclopentadiene and methyl bromoacetate in tetrahydrofuran by the method of J. J. Partridge [J. Am. Chem. Soc., 95, 7171 (1973)].

Sources & evidence

ORD record
ord-07c9b58aa36d4455ab9ffa0363ac6ebd
Source dataset
uspto-grants-1980_11
Patent number
US04233222

Reaction notes

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