Hydrogen Peroxide → HCID 12951084, compound

HRID 2285859Notes

Reaction equation

HRID 2285859 reaction equation
FC(F)(F)C([O:5][C:6](=[O:11])[C:7]([F:10])([F:9])[F:8])=O.OO.[F:16][C:17]([F:47])([C:43]([F:46])([F:45])[F:44])[C:18]([F:42])([F:41])[C:19]([F:40])([F:39])[C:20]([F:38])([F:37])[C:21]([F:36])([F:35])[C:22]([F:34])([F:33])[C:23]([F:32])([F:31])[C:24]([F:30])([F:29])[C:25]([I:28])([F:27])[F:26]>FC(F)(F)C(O)=O>[F:8][C:7]([F:10])([F:9])[C:6]([O:11][I:28]([O:5][C:6](=[O:11])[C:7]([F:8])([F:9])[F:10])[C:25]([F:27])([F:26])[C:24]([F:30])([F:29])[C:23]([F:32])([F:31])[C:22]([F:34])([F:33])[C:21]([F:36])([F:35])[C:20]([F:37])([F:38])[C:19]([F:40])([F:39])[C:18]([F:41])([F:42])[C:17]([F:47])([F:16])[C:43]([F:44])([F:45])[F:46])=[O:5]

Participants

5

Reactant 3

HCID 784Hydrogen PeroxideHCID 9845Trifluoroacetic anhydrideHCID 67920Perfluorodecyl iodide

Product 1

HCID 12951084HCID 12951084, compoundYield 94%

Reagents, catalysts & solvents 1

HCID 6422Trifluoroacetic acidSolvent

Procedure

To a mixture of 10.6 ml (75.2 mmols) of trifluoroacetic anhydride and 30 ml of trifluoroacetic acid was added dropwise 1.36 ml of a 35% aqueous hydrogen peroxide solution (H2O2, 15.7 mmols and H2O, 55 mmols) in an ice bath. After completion of addition, the mixture was stirred for 1.5 hour and 5.0 g (7.7 mmols) of heneicosafluoro-n-decyl iodide was added thereto, followed by allowing the mixture to react at 0° to 5° C. for 24 hours. The solvent was then distilled off to obtain 6.3 g (94% yield) of di(trifluoroacetoxy)iodoheneicosafluoro-n-decane as white fluffy crystals.

Workup

  1. additionAfter completion of addition
  2. customto react at 0° to 5° C. for 24 hours
  3. distillationThe solvent was then distilled off

Sources & evidence

ORD record
ord-041c13a23f524021974eae52d84a70cb
Source dataset
uspto-grants-1982_04
Patent number
US04324741

Reaction notes

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