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HRID2291431

反应详情

EQUATION

反应方程式

HRID 2291431 的结构方程式

REACTANTS

反应物

3
结构：CN(C)C=O
HCID6228

N,N-Dimethylformamide

C3H7NO

结构：O=P(Cl)(Cl)Cl
HCID24813

Phosphoric trichloride

Cl3OP

结构：CC(=O)OCCN(CCOC(C)=O)c1ccccc1
HCID29521

2,2'-(Phenylimino)bisethyl diacetate

C14H19NO4

PRODUCTS

生成物

1
结构：CC(=O)OCCN(CCOC(C)=O)c1ccc(C=O)cc1
HCID328729

4-[Bis[2-(acetyloxy)ethyl]amino]benzaldehyde

C15H19NO5

收率 93%

PROCEDURE

实验过程

N,N-Di-(2-acetoxyethyl)aniline (A6) (126 g, 0.476 mol) was reacted with phosphorous oxychloride (80.3 g, 0.524 mol) in DMF as for A2 in Example 3. The product was distilled at 155°-175° C. (0.15 mm) to yield 130 g (93%) of A7 as an orange oil.

WORKUP

后处理

  1. distillationThe product was distilled at 155°-175° C. (0.15 mm)