Benzoic Acid → HCID 21930739, compound

HRID 2296598Notes

Reaction equation

HRID 2296598 reaction equation
[C:1]([OH:9])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH:10]([O:12][CH2:13][CH2:14]Cl)=[CH2:11].[OH-].[Na+].C(N(CC)CC)C>C1(C)C=CC=CC=1.[Br-].C([N+](CCCC)(CCCC)CCCC)CCC>[CH:10]([O:12][CH2:13][CH2:14][O:8][C:1](=[O:9])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)=[CH2:11]

Participants

7

Reactant 4

HCID 243Benzoic AcidHCID 80742-Chloroethyl vinyl etherHCID 8471TriethylamineHCID 14798Sodium Hydroxide

Product 1

HCID 21930739HCID 21930739, compound

Reagents, catalysts & solvents 2

HCID 74236Tetrabutylammonium BromideCatalystHCID 1140TolueneSolvent

Conditions

Temperature
120 °C

Procedure

Benzoic acid (244 g) (2 mol) was dissolved in 3,000 ml of toluene, and thereto were added 320 g of 2-chloroethyl vinyl ether, 88 g of sodium hydroxide, 25 g of tetrabutylammonium bromide, and 100 g of triethylamine. The resulting mixture was stirred with heating at 120° C. for 5 hours.

Sources & evidence

ORD record
ord-418306255f36449a96863edfa193ae18
Source dataset
uspto-grants-2002_12
Patent number
US06489080B2

Reaction notes

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