Azobisisobutyronitrile → HCID 86583983, compound

HRID 2296887Notes

Reaction equation

HRID 2296887 reaction equation
[OH:1][CH2:2][CH2:3][CH2:4][O:5][C:6](=[O:9])[CH:7]=[CH2:8].[CH3:10][O:11][C:12](=[O:16])[C:13]([CH3:15])=[CH2:14].CC(N=NC(C#N)(C)C)(C#N)C>C1COCC1>[OH:1][CH2:2][CH2:3][CH2:4][O:5][C:6](=[O:9])[CH:7]=[CH2:8].[CH3:10][O:11][C:12](=[O:16])[C:13]([CH3:15])=[CH2:14]

Participants

5

Reactant 3

HCID 6547AzobisisobutyronitrileHCID 6658Methyl MethacrylateHCID 331012-Propenoic acid, 3-hydroxypropyl ester

Product 1

HCID 86583983HCID 86583983, compoundYield 81%

Reagents, catalysts & solvents 1

HCID 8028TetrahydrofuranSolvent

Conditions

Temperature
67.5 °C

Procedure

To a 500 ml round-bottom flask was added 0.3 mole of 9-anthracenemethylmethacrylate, 0.5 mole of 3 -hydroxypropylacrylate, 0.2 mole of methylmethacrylate, 300 g of THF, and 0.1-3 g of AIBN. The resulting solution was stirred at 60-75° C. for 5-20 hours under nitrogen atmosphere. The reaction mixture was precipitated in ethyl ether or n-hexane. The precipitate was filtered and dried to provide poly[9-anthracenemethylmethacrylate/3-hydroxypropylacrylate/methylmethacrylate] copolymer of Formula 23. Yield: 81%.

Workup

  1. customThe reaction mixture was precipitated in ethyl ether
  2. filtrationThe precipitate was filtered
  3. customdried

Sources & evidence

ORD record
ord-791b10020faf4e2a9ebb10d09ca9a4fd
Source dataset
uspto-grants-2002_12
Patent number
US06489432B2

Reaction notes

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